Radical Deoxygenaton of Secondary and Primary Alcohols with Phenylsilane
- 1 January 1991
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1991 (06) , 435-438
- https://doi.org/10.1055/s-1991-20755
Abstract
Thionocarbonates and xanthates formed from secondary and primary alcohols are easily deoxygenated in 85-100% yield by radical deoxygenation with phenylsilane and 2,2′ -azobisisobutyronitrile or benzoyl peroxide in boiling toluene.Keywords
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