Cyclization of Aryl Acyl Radicals Generated fromS-(4-Cyano)phenyl Thiolesters by a Nickel Complex Catalyzed Electroreduction
- 1 May 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 68 (11) , 4586-4589
- https://doi.org/10.1021/jo0268512
Abstract
Aromatic acyl radicals generated from S-(4-cyano)phenyl 2-alkenylthiobenzoate by a nickel complex catalyzed electroreduction undergo 5- and 6-exo cyclization to give 1-indanone and dihydro-1-naphthalenone derivatives, respectively.Keywords
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