PREPARATION AND CHARACTERIZATION OF OXO(2,3,17,18-TETRAMETHYL-7,8,12,13-TETRAETHYLCORROLATO)MOLYBDENUM(V)
- 5 June 1977
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 6 (6) , 689-692
- https://doi.org/10.1246/cl.1977.689
Abstract
Oxo(2,3,17,18-tetramethyl-7,8,12,13-tetraethylcorrolato)molybdenum(V) was prepared from the corresponding corrole by the reaction with either molybdenum pentachloride or molybdenum hexacarbonyl. Spin Hamiltonian parameters were evaluated as g = 1.967, AMo=41.8×10−4 cm−1, and AN=2.3×10−4 cm−1. The results from ESR and ESCA measurements indicate that the molybdenum complex has a compressed tetragonal structure of N4O-coordination.This publication has 4 references indexed in Scilit:
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