Reaction of C60 with α-Diazoketones: Methano- and Dihydrofuranofullerenes
- 1 August 1996
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1996 (08) , 729-730
- https://doi.org/10.1055/s-1996-5510
Abstract
The reaction of C60 2 with α-diazoketones 1 leads to 6,6-bridged, closed 1,2-methano[60]fullerenes 4a - e and - after their rearrangement on the C60 surface - to 2’-substituted 6,6-bridged, closed 1,2-dihydro-(4’,5’-dihydrodurano)-[60]fullerenes 5a, d, e.Keywords
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