Ionic conductivity of polymer electrolytes and future applications
- 1 January 1988
- journal article
- research article
- Published by Wiley in British Polymer Journal
- Vol. 20 (3) , 181-192
- https://doi.org/10.1002/pi.4980200304
Abstract
Polymer electrolytes are solvent‐free ion‐conducting polymers and provide new and attractive materials in both polymer chemistry and electrochemistry. A proper understanding of ion dissociation and ion transport in such polymers is necessary for their application as solid electrolytes in electrochemical devices. Ionic conduction behaviour in polymer electrolytes is described here in relation to the characteristic properties. Of special interest is the ability of polymer electrolytes to include various kinds of electroactive molecules within them. The combination of this ability with their high ionic conductivity has enabled polymer electrolytes to be used as media for electrochemical syntheses and redox reactions.Keywords
This publication has 76 references indexed in Scilit:
- Structure-conductivity relationsihp in polymer electrolytes formed by network polymers from poly[dimethylsiloxane-g- poly(ethylene oxide)] and litegum perchlorateJournal of Power Sources, 1987
- Carrier transport and generation processes in polymer electrolytes based on poly(ethylene oxide) networksMacromolecules, 1987
- Characteristics of Electro-Optic Device Using Conducting Polymers, Polythiophene and Polypyrrole FilmsJapanese Journal of Applied Physics, 1983
- Conductivity, charge transfer and transport number—an ac-investigation of the polymer electrolyte LiSCN-poly(ethyleneoxide)Electrochimica Acta, 1982
- Ionic conductivity of macromolecular networks I — Polyether filled with sodium tetraphenylborideMaterials Research Bulletin, 1980
- The Thermodynamics of Ion Association in Solution. I. An Extension of the Denison-Ramsey EquationsJournal of the American Chemical Society, 1966
- Dipole Moments of Chain Molecules. I. Oligomers and Polymers of OxyethyleneJournal of the American Chemical Society, 1966
- The Configuration of the Polyoxyethylene ChainJournal of the American Chemical Society, 1965
- The Temperature Dependence of Relaxation Mechanisms in Amorphous Polymers and Other Glass-forming LiquidsJournal of the American Chemical Society, 1955
- The Diffusion of Gases Through Polyvinyl Acetate1Journal of the American Chemical Society, 1954