Pulse Radiolysis of Dioxane Solutions
- 30 April 1965
- journal article
- other
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 148 (3670) , 637-638
- https://doi.org/10.1126/science.148.3670.637
Abstract
Liquid dioxane gives transient absorptions owing to the production of free radicals and solvated electrons when subjected to a pulse of high-energy electrons (4 million electron volts) for a duration of 2 microseconds. Solutions of benzophenone give the ketyl radical and ketyl radical ions. Solutions of anthracene give anthracene in the triplet state and the anthracene anion. The formation of these species is largely prevented when hydrochloric acid is present.Keywords
This publication has 5 references indexed in Scilit:
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- Pulse radiolysis apparatusJournal of Scientific Instruments, 1964
- Decay Kinetics of the 1-Naphthaldehyde and Benzophenone Triplet States in BenzeneJournal of the American Chemical Society, 1963
- Pulse radiolysis studies of the reactivity of the solvated electron in ethanol and methanolDiscussions of the Faraday Society, 1963
- Absorption Spectrum of the Hydrated Electron in Water and in Aqueous SolutionsJournal of the American Chemical Society, 1962