Electronic Energy Levels of the Trivalent Lanthanide Aquo Ions. III. Tb3+
- 15 November 1968
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 49 (10) , 4447-4449
- https://doi.org/10.1063/1.1669895
Abstract
A total of 23 experimental “free‐ion” energy levels of Tb3+ (aquo) have been fit with an rms deviation of 56 cm−1. The resulting parameters are: , and . The latter three parameters arise from including the effects of configuration interaction in the calculation. Assignments were based upon a correlation between calculated and observed band intensities at energies up to ≈40 000 cm−1.
Keywords
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