Kinetics and equilibria of the S-nitrosation of alkylthioureas
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 15,p. 1734-1736
- https://doi.org/10.1039/p29750001734
Abstract
The equilibrium constants for the addition of the nitrosonium ion to the sulphur atom of a range of alkylthioureas have been measured, and shown to correlate well with the ionisation constants of the corresponding conjugate acids. Stopped-flow studies of the rate of reaction show it to occur by an encounter-controlled process.Keywords
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