Electron spin resonance of bis(NN-diethylthiocarbamato)nitrosyliron
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2572-2575
- https://doi.org/10.1039/j19690002572
Abstract
The e.s.r. parameters for Fe(NO)(S2CNEt2)2 have been measured at Q, X, and S-band frequencies and the g-tensor and A(14N) and A(57Fe) hyperfine tensors have been deduced. The results are best accommodated if the unpaired electron is in an a1′(dz2) orbital and the order of energy levels is a2 < b1 < b2 < a1′ < a1″. Small differences between the results at different frequencies are discussed in terms of deviations from linearity for the Fe–N–O unit.Keywords
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