Two new ten-vertex arachno mixed-atom diheteroboranes, 6,9-CNB8H13and 6,9-CSB8H12
- 1 January 1991
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1389-1390
- https://doi.org/10.1039/c39910001389
Abstract
Treatment of the monocarbaborane arachno-4-CB8H14 with either sodium nitrite or elemental sulphur in the presence of triethylamine results in the isolation of two representatives of the ten-vertex arachno family of cluster carbaheteroboranes, 6,9-CNB8H13 and 6,9-CSB8H12, the constitution of which has been established on the basis of 1H, 11B, [11B–11B]-COSY, and [1H–1H]-COSY NMR data and mass spectroscopic measurements.Keywords
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