High resolution infra-red studies of HCCCN and DCCCN
- 1 August 1976
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 32 (2) , 473-485
- https://doi.org/10.1080/00268977600103231
Abstract
A total of 15 bands of HCCCN and 10 bands of DCCCN, occurring in the region 1800–6500 cm-1, have been recorded at resolutions of between 0·025 and 0·050 cm-1. Sufficient fundamental, overtone, combination and hot bands have been analysed to enable accurate band origins to be determined for v 1, v 2, v 3, v 5, v 6 and v 7 of both isotopic species and to enable estimates of the band origins of v 4 of both isotopic species to be made. The rotational structure of 37 bands has been analysed to yield accurate values of vi 0, (B′-B″) and in some cases, (D′-D″).Keywords
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