[NdI2(thf)5], the First Crystallographically Authenticated Neodymium(II) Complex
- 3 September 2001
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 40 (17) , 3176-3178
- https://doi.org/10.1002/1521-3773(20010903)40:17<3176::aid-anie3176>3.0.co;2-y
Abstract
Two new starting materials for a new chemistry of low-valent lanthanide compounds are the first crystallographically characterized molecular complexes of the rare Nd2+ ion, [NdI2(thf)5] (1), and [TmI2(thf)(dme)2] (2; dme=1,2-dimethoxyethane). These have a pentagonal-bipyramidal structure in which the two iodine atoms are in axial positions.This publication has 22 references indexed in Scilit:
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