A Thermistor Method for the Determination of Velocity Coefficients of Vinyl Polymerization. IV
- 1 January 1957
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 30 (1) , 10-13
- https://doi.org/10.1246/bcsj.30.10
Abstract
Concentration change of sensitizer during vinyl acetate polymerization photosensitized by 1, 1′-azo-biscyclohexanecarbon-itrile was measured with use of a spectro-photometer and the initiation velocity of polymerization was determined. Values of kp and kt at various degree of conversion were calculated from this value and the results of the previous paper. From this experiment, it was concluded that kp was nearly constant up to 40% conversion and as the conversion exceeded 40%, it decreased, while kt gradually decresed with the increase of the conversion.This publication has 5 references indexed in Scilit:
- A Thermistor Method for the Determination of Velocity Coefficients of Vinyl Polymerization. HIBulletin of the Chemical Society of Japan, 1956
- A Thermistor Method for the Determination of Velocity Coefficients of Vinyl Polymerization. IIBulletin of the Chemical Society of Japan, 1956
- A Thermistor Method for the Determination of Velocity Coefficients of Vinyl Polymerization. IBulletin of the Chemical Society of Japan, 1956
- A thermocouple method of following the non-stationary state of chemical reactions - II. The evaluation of velocity coefficients and energies of activation for the propagation and termination reactions for the initial and later stages of the polymerization of vinyl acetateProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1955
- Rate Constants in Free Radical Polymerization. III. Styrene1Journal of the American Chemical Society, 1951