Polarographic Behaviour of Transition Metal Nitrosyl Complexes in Nonaqueous Media. IV. Cyclopentadienylnitrosylnickel
Open Access
- 1 August 1970
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 25 (8) , 786-789
- https://doi.org/10.1515/znb-1970-0804
Abstract
The polarographic reduction of C5H5NiNO in DMF and ACN has been investigated. The first step of reduction involves an irreversible transfer of one electron to form an instable radical anion. On the basis of polarographic, voltammetric and coulometric measurements an overall mechanism is suggested.Keywords
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