Chiral spiro-connected 2,3,3-trisubstituted oxiranes New dopants for induced ferroelectric phases

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Abstract
The synthesis, phase behaviour and spontaneous polarization of a new class of chiral dopants for induced ferroelectric phases of general structure A and B, possessing a 2,3,3-trisubstituted oxirane ring spiro-connected with four-, five- or six-membered carbocycles are described. In a series of these compounds with the same mesogenic building blocks the one with the five-membered carbocycle exhibits the highest induced spontaneous polarization. Introduction of a carbonyl group adjacent to the oxirane ring leads to an increased induced spontaneous polarization. The sign of the helical twisting power is positive for compounds with a cyclobutane ring and negative for those with a cyclopentane or a cyclohexane ring, although the absolute configuration at the chiral carbon is the same for all compounds.

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