The nature of ‘chloroferric phthalocyanine’
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1546-1550
- https://doi.org/10.1039/j19700001546
Abstract
Experiments in dimethyl sulphoxide and dimethylacetamide show that ‘chloroferric phthalocyanine’ is most probably a hydrochloride of ferrous phthalocyanine. Evidence is presented to show that chloride ion is acting as an axial ligand at a ferrous centre. The proton modifies the phthalocyanine ring, presumably being attached to an azomethine bridge. These results are discussed in the light of previous ones.Keywords
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