The temperature-independent paramagnetism of permanganate and related complexes
- 1 May 1960
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 3 (3) , 271-275
- https://doi.org/10.1080/00268976000100311
Abstract
The temperature-independent paramagnetism of permanganate is discussed in terms of molecular orbital theory. It is shown that the major contribution to the paramagnetism arises from electrons in metal d orbitals, and that the amount of charge-transfer from the ligands to the metal ion can be estimated. The theory is applicable to any complex in which the metal ion possesses vacant low-lying d orbitals.Keywords
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