Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct
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- 2 October 2007
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 47,p. 5072-5074
- https://doi.org/10.1039/b710475h
Abstract
A four-membered cyclic intramolecular phosphane–borane adduct activates dihydrogen to yield the respective ethylene-bridged zwitterionic phosphonium–hydridoborate system, which reduces benzaldehyde.Keywords
This publication has 25 references indexed in Scilit:
- Facile Heterolytic Cleavage of Dihydrogen by Phosphines and BoranesJournal of the American Chemical Society, 2007
- Reversible, Metal-Free Hydrogen ActivationScience, 2006
- Homogeneous, Titanocene-Catalyzed Dehydrocoupling of Amine−Borane AdductsJournal of the American Chemical Society, 2006
- Stereochemistry of Imine Reduction by a Hydroxycyclopentadienyl Ruthenium HydrideJournal of the American Chemical Society, 2006
- Comparing Nickel- and Palladium-Catalyzed Heck ReactionsOrganometallics, 2004
- Toward efficient asymmetric hydrogenation: Architectural and functional engineering of chiral molecular catalystsProceedings of the National Academy of Sciences, 2004
- Stoichiometric, Catalytic, and Enantioface-Selective Hydrogenation of CN Bonds by an Ionic MechanismJournal of the American Chemical Society, 2001
- Asymmetric Transfer Hydrogenation Catalyzed by Chiral Ruthenium ComplexesAccounts of Chemical Research, 1997
- [33] Oxygen-stable hydrogenase and assayPublished by Elsevier ,1978
- The Mechanism of Action of the Enzyme Hydrogenase1Journal of the American Chemical Society, 1954