Stereochemistry of formation and reduction of π-allyl palladium chloride complexes from steroidal olefins
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 165-166
- https://doi.org/10.1039/c39750000165
Abstract
The regioselectivity and stereoselectivity of palladium π-allyl chloride complex formation from steroidal olefins was apparently controlled by steric effects, and both cholest-4-ene and cholest-5-ene gave diastereoisomeric complexes; two of the complexes were reduced to olefins by lithium aluminium hydride stereo-specifically with retention of configuration.Keywords
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