1-Methyluracil (Hmeu) as tetradentate ligand: crystal structure of trans-(NH3)2Pt(meu)2Ag2(NO3)2(H2O)·H2O
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 769-770
- https://doi.org/10.1039/c39840000769
Abstract
In the heteronuclear complex trans-(NH3)2Pt(C5H5N2O2)2Ag2(NO3)2(H2O)·H2O trinuclear Pt, Ag2,L2(L1-meth uracil anion, meu)units, containing Pt Co-ordinating to N(3) of meu and Ag atoms bound through mixed O(4), O(2)co-ordination, are linked through additional binding between O(4) of meu and Ag of the adjacent molecule, thus creating a polymeric arrangement of Pt,Ag2L2 with tetradentate meu and bridging O(4) oxygens.Keywords
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