Kinetic resolution of secondary alcohols via chiral Pd(ii)-complex-catalysed enantioselective benzoylation using CO and organobismuth(v) compound

Abstract
A novel method for kinetic resolution of racemic secondary alcohols via their enantioselective benzoylation (up to 48% ee) has been explored using CO, Ph3Bi(OAc)2, a catalytic amount of chiral Pd(II)-complex and AgOAc.

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