New routes to copper–lanthanoid complexes I: via a metallomacrocycle
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1453-1455
- https://doi.org/10.1039/c39910001453
Abstract
We report the synthesis and structure of a novel hexanuclear copper complex of the anion of 6-methyl-2-hydroxypyridine (MeL), which undergoes reaction with lanthanum nitrate to give [La8Cu12(OH)24(NO3)22(MeLH)13(H2O)6][NO3]2[MeLH]2·CH2Cl2, a copper–lanthanoid complex with several unique structural features.Keywords
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