Metal-semiconductor fluctuation in the Sn adatoms in the Si(111)-Sn and Ge(111)-Sn (√3×√3)R30° reconstructions

Abstract
The two components of the Sn 4d core level in the Si(111)-Sn and Ge(111)-Sn (√3×√3)R30° structures are proposed to arise from semiconductor-metal fluctuations in the Sn adatom layer. Adsorption of potassium on the Si(111)-Sn (√3×√3)R30° surface suppresses the metallic component and shifts the tin into a purely semiconducting phase with a filled dangling bond state.

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