Thermal Diffusion near the Critical Solution Point
- 1 July 1956
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 25 (1) , 32-33
- https://doi.org/10.1063/1.1742842
Abstract
Thermal diffusion measurements have been carried out near the critical solution point by means of a new apparatus which will be described in another paper. The Soret coefficient D′/D for nitrobenzene+n-hexane shows a large increase in the vicinity of this point. This is a strong argument in favor of the existence of a thermodynamical factor in the isothermal diffusion coefficient as predicted by the thermodynamics of irreversible processes.Keywords
This publication has 1 reference indexed in Scilit:
- Étude des systèmes binaires hétérogènes propriétés physiques des systèmes liquides à deux couches (II)Journal de Chimie Physique et de Physico-Chimie Biologique, 1934