Syntheses and Photochemically Induced Rearrangements of Tetrasilyl- and Trisilylgermyl Complexes of Iron: (η5-C5R5)Fe(CO)2(SiMe2)3EMe2Ph (R = H, Me; E = Ge, Si)
- 1 March 2000
- journal article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 19 (7) , 1225-1231
- https://doi.org/10.1021/om990897c
Abstract
No abstract availableThis publication has 21 references indexed in Scilit:
- Synthesis and Properties of Intramolecularly Base-Stabilized (Disilanyl−silylene)ruthenium and -iron ComplexesOrganometallics, 1998
- Synthesis of a Donor-Stabilized Silyl(silylene)iron Complex. Direct Observation of 1,3-Methyl Migration from Silyl to Silylene LigandsChemistry Letters, 1996
- Transition-metal-catalyzed silylene expulsion from, and/or rearrangement of, oligosilanesOrganometallics, 1994
- Photochemical synthesis and stereodynamic behavior of alkoxy-bridged (silylene)(germylene)iron complexesOrganometallics, 1992
- Organometalloidal derivatives of the transition metals. 29. Photochemical transformations of digermyl and isomeric silylgermyl and germylsilyl complexes of the (.eta.5-C5H5)Fe(CO)2 system. Significant stability of germylene versus silylene intermediatesOrganometallics, 1991
- Direct evidence for the formation of a disiladiferracyclic compound through dimerization of an iron-silylene intermediateOrganometallics, 1991
- Photolysis of alkoxy-substituted disilanyliron complexes: preparation of donor-stabilized bis(silylene)iron complexes and the crystal structure of [cyclic] (Me2Si)[(.eta.5-C5Me5)Fe(CO)][SiMe(OMe)]OMeJournal of the American Chemical Society, 1990
- Photochemical skeletal redistributions of permethylated linear and cyclic oligosilyl groups in (.eta.5-C5H5)Fe(CO)2-substituted oligosilanesOrganometallics, 1989
- Synthesis, characterization, and x-ray crystal structure of a donor-stabilized bis(silylene)iron complexJournal of the American Chemical Society, 1988
- Organometalloidal derivatives of the transition metals. 12. Polysilane-metal interactions. Photochemical deoligomerizations and base treatment migrations from iron to cyclopentadienyl ligandsOrganometallics, 1986