Enzymes in organic synthesis. 26.Synthesis of enantiomerically pure grandisol from an enzyme-generated chiral synthon
- 1 August 1982
- journal article
- research article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 60 (15) , 2007-2011
- https://doi.org/10.1139/v82-283
Abstract
The synthesis of enantiomerically pure (+)-grandisol has been achieved from an enzymically generated chiral synthon. The synthesis is an efficient one, the yield of optically pure material being 12% up to the penultimate step and 3% overall.This publication has 3 references indexed in Scilit:
- Oxycyclopropanes in organochemical synthesis. Total syntheses of (-)-valeranone and (.+-.)-grandisolJournal of the American Chemical Society, 1978
- Insect Pheromone Synthesis: New MethodologyScience, 1976
- Studies on terpenes. 4. Synthesis of optically active grandisol, the boll weevil pheromoneJournal of the American Chemical Society, 1976