The first oligopeptide derivative of 1′-aminoferrocene-1-carboxylic acid shows helical chirality with antiparallel strands
- 11 August 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 17,p. 2004-2005
- https://doi.org/10.1039/b407771g
Abstract
The unnatural organometallic amino acid 1′-aminoferrocene-1-carboxylic acid (Fca) induces a turn structure in a tetrapeptide with anti-parallel strands which is stabilized by two intra-molecular hydrogen bonds in the solid state and in solution.Keywords
This publication has 20 references indexed in Scilit:
- Main Chain Ferrocenyl Amides from 1‐Aminoferrocene‐1′‐carboxylic AcidEuropean Journal of Inorganic Chemistry, 2004
- Circular dichroism spectra of planar chiral 2-substituted ferrocenecarboxaldehydes and 2-ferrocenyl-1,1-dicyanoethylenesTetrahedron: Asymmetry, 2003
- Organometallic β-turn mimetics. A structural and spectroscopic study of inter-strand hydrogen bonding in ferrocene and cobaltocenium conjugates of amino acids and dipeptidesDalton Transactions, 2003
- Intramolecular Conformational Control in Ferrocenes Bearing Podand Dipeptide ChainsOrganometallics, 2001
- An Amide-Linked Ferrocene Dimer, [(CH3CONHC5H4)Fe(C5H4CONHC5H4)Fe(C5H4CONHCH3)]. Formation of Inter- and Intramolecular NH···OC Hydrogen BondsInorganic Chemistry, 1998
- A highly ordered ferrocene system regulated by podand peptide chainsChemical Communications, 1998
- The Isocyanate Route to Cyclopentadienyl-Carboxamide- and Cyclopentadienyl-Amino Ester-Substituted Metallocene ComplexesOrganometallics, 1996
- Anatomy of a stable intramolecularly hydrogen bonded folding patternJournal of the American Chemical Society, 1991
- Conformation-directing effects of a single intramolecular amide-amide hydrogen bond: variable-temperature NMR and IR studies on a homologous diamide seriesJournal of the American Chemical Society, 1991
- Synthesis of 1,1'-bis(2-amino-2-carboxyethyl)ferrocene [1,1'-ferrocenyl bis(alanine)]The Journal of Organic Chemistry, 1990