An Efficient Indium-Mediated Synthesis of α-Cyano-β-Ethylenic Secondary Alcohols in Water
- 1 September 1996
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 26 (17) , 3179-3191
- https://doi.org/10.1080/00397919608004627
Abstract
Coupling of aldehydes with 3-bromo-1-cyano-1-propene, using indium in water, is a very convenient method to prepare α-cyano-β-ethylenic secondary alcohols.Keywords
This publication has 13 references indexed in Scilit:
- Synthetic Organoindium Chemistry: What Makes Indium so Appealing?Synlett, 1995
- Indium-Mediated Coupling of .alpha.-(Bromomethyl)acrylic Acid with Carbonyl Compounds in Aqueous Media. Concise Syntheses of (+)-3-Deoxy-D-glycero-D-galacto-nonulosonic Acid and N-Acetylneuraminic AcidThe Journal of Organic Chemistry, 1995
- A new and direct access to glycono-1,4-lactones from glycopyranoses by regioselective oxidation and subsequent ring restrictionTetrahedron Letters, 1995
- 1993 R.U. Lemieux Award Lecture Organometallic-type reactions in aqueous media—a new challenge in organic synthesisCanadian Journal of Chemistry, 1994
- Water-Promoted Organic ReactionsSynthesis, 1994
- Organic reactions in aqueous media - with a focus on carbon-carbon bond formationChemical Reviews, 1993
- Organometallic reactions in aqueous media with indiumTetrahedron Letters, 1991
- Préparation et utilisation d'un nouveau synthon acétylénique symétrique ou dissymétrique : le monoacétal de l'acétyl'`enedicarbaldéhyde.Tetrahedron Letters, 1979
- The reactivity of allylic organometallic compounds of lithium, sodium, magnesium, zinc, cadmium and aluminium: Recent advancesJournal of Organometallic Chemistry, 1974
- Neuere Ergebnisse in der Vitamin‐A‐ReiheAngewandte Chemie, 1960