New cobalt(I) complexes derived from dicarbonyltricyanocobaltate(I)

Abstract
The preparation and characterization of several series of mixed ligand cobalt(I) complexes of the types [Co(CN)2(CO)2(PR3)], [Co(CN)2(CO)(PR3)2], and [Co(CN)(CO)2(PR3)2], prepared by the reactions of tertiary phosphines (PR3) with [Co(CN)3(CO)2]2–, are described and some novel aspects of their chemistry are discussed.

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