Asymmetric Dihydroxylation (AD) of α,β-Unsaturated Ketones
- 1 January 1993
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1993 (08) , 605-606
- https://doi.org/10.1055/s-1993-22548
Abstract
The asymmetric dihydroxylation of α,β-unsaturated ketones has been investigated and found to give the corresponding α,β-dihydroxy ketones in good yields and excellent enantiomeric excesses. The problem of epimerization of the α-carbon has been eliminated by employing a buffered AD-mix containing sodium bicarbonate.Keywords
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