Transition-metal dithiolene complexes. Part XX. Dicyano-1,2-dithiolene complexes of rhenium
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 712-713
- https://doi.org/10.1039/j19710000712
Abstract
A voltammetric study of the complex previously formulated as [Re{S2C2(CN)2}2]2 2– has shown that it must be reformulated as [Re{S2C2(CN)2}2]4 4–, which undergoes one one-electron reduction and two one-electron oxidation processes. Oxidation of [Re{S2C2(CN)2}3]2– with iodine afforded [ReO{S2C2(CN)2}2]–, which may be reduced voltammetrically to a dianion.Keywords
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