Homogeneous olefin hydrogenation over oxidized rhodium complexes
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 9,p. 571-572
- https://doi.org/10.1039/c29700000571
Abstract
Hydrogenation of the previously reported oxides obtained from oxidation of [Rh(Ph3P)Cl] in ethanol and benzene gives materials capable of olefin hydrogenation but double-bond isomerization occurs during the reaction: hydrogenation of these species in the presence of Ph3P gives catalysts which are not only much more active toward olefin hydrogenation but also inhibit isomerization.Keywords
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