Preparation and properties of inclusion compounds of transition metal complexes of cyclo-octa-1,5-diene and norbornadiene with cyclodextrins
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1229-1230
- https://doi.org/10.1039/c39860001229
Abstract
2 : 1 (cyclodextrin : guest) inclusion compounds were obtained in high yields by the treatment of β-cyclodextrin (β-CD) with [(L)RhCl]2(L = norbornadiene or cyclo-octa-1,5-diene, cod) and 1:1 inclusion compounds were obtained by the reaction of β-CD with (cod)PtX2(X = Cl, Br, or I) in high yields, while γ-CD formed 1:1 inclusion compounds with (cod)PtX2(X = Br or I); the formation of inclusion compounds is selective.Keywords
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