Derivation of p-C-T relationships for the Pd+Ni+H and Pd+Rh+H systems at pressures exceeding atmospheric from measurements of electrode potential
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 62, 971-978
- https://doi.org/10.1039/tf9666200971
Abstract
Pressure-composition (p-C) relationships for pressures of hydrogen up to 15 atm have been derived for the hydrides of some Pd+Ni and Pd+Rh alloys from measurements of electrode potential subsequent to electrolysis. Relationships between H/Me and R/R0 also have been derived. Heats and entropies of absorption and desortion of hydrogen have been calculated over regions of hydrogen content where there is evidence that α- and β-phase hydrides co-exist.Keywords
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