First Crystal Structure Analysis of an Aliphatic Carbocation—Stabilization of the 3,5,7‐Trimethyl‐1‐adamantyl Cation by C-C Hyperconjugation
- 1 April 1986
- journal article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 25 (4) , 349-350
- https://doi.org/10.1002/anie.198603491
Abstract
No abstract availableKeywords
This publication has 13 references indexed in Scilit:
- Relative reactivity of bridgehead adamantyl and homoadamantyl substrates from solvolyses with heptafluorobutyrate as a highly reactive carboxylate leaving group. Absence of SN2 character of solvolysis of tert-butyl derivativesJournal of the American Chemical Society, 1985
- Coordination of a "noncoordinating" anion: x-ray crystal structure and phosphorus-31 NMR characterization of a tungsten nitrosyl cation ligated to hexafluoroantimonate(1-) ionJournal of the American Chemical Society, 1985
- Bridgehead adamantyl, diamantyl, and related cations and dicationsJournal of the American Chemical Society, 1985
- Polar Effects. X. Polar Substituent Effects in the Solvolysis of 3‐Substituted 1‐Adamantyl Bromides and ToluenesulfonatesHelvetica Chimica Acta, 1982
- Structural Studies of Crystalline EnaminesHelvetica Chimica Acta, 1978
- Inductive, Hyperconjugative and Frangomeric Effects in the Solvolysis of 1‐Substituted 3‐Bromoadamantanes. Polar effects IVHelvetica Chimica Acta, 1978
- Crystal structure, Raman spectrum, and nuclear magnetic resonance spectrum of methoxythionyl .mu.-fluoro-bis(pentafluoroantimonate(V)), CH3OSO+Sb2F11-Journal of the American Chemical Society, 1976
- Crystal Structure of 1-Cyanotetracyclo[3.3.1.13,7.03,7]decaneCanadian Journal of Chemistry, 1973
- Preparative Carbocation Chemistry; VII1. Isolation of Alkyl(cycloalkyl)carbenium Ion Salts: Trimethylcarbenium (t-Butyl), Tricyclopropylcarbenium, and 1-Adamantyl Fluoroantimonates.Synthesis, 1973
- The crystal structure of adamantane: an example of a false minimum in least squaresActa Crystallographica, 1967