Unique intramolecular exchange between H of SiHPh2 and SAr in [RhH(SiHPh2)(SAr)(PMe3)3]
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 2315-2316
- https://doi.org/10.1039/c39950002315
Abstract
mer-iRhH[SiHPh2(SAr)(PMe3)3], prepared from oxidative addition of H2SiPh2 to Rh(SAr)(PMe3)3, undergoes transfer of the thiolato ligand to the coordinated Si atom to give fac-[RhH2{SiPh2(SAr)}(PMe3)3].Keywords
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