Notizen:Einige Bemerkungen zur Stabilität von WO2F2 / Remark on the stability of WO2F2
Open Access
- 1 October 1978
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung A
- Vol. 33 (10) , 1239-1240
- https://doi.org/10.1515/zna-1978-1023
Abstract
Based on equilibrium calculations on the W-O-F system [6], in which WO2F2 was found to be the predominant low temperature species, an attempt was made to synthesize WO2F2 from WO2 + NF3. However, yields of WOF4 instead of WO2F2 were obtained. This discrepancy between theory and experiment is shown to be due to an error in the estimation of the thermodynamic data of WO2F2 [1].Keywords
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