Oxidative Transfer Dehydrogenation of α,β-Unsaturated Carbinols to α,β-Unsaturated Ketones Catalyzed by Ruthenium Complexes
- 15 November 1974
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 52 (22) , 3825-3827
- https://doi.org/10.1139/v74-572
Abstract
The homogeneous competitive intermolecular and intramolecular hydrogen transfer from unsaturated carbinols to vinyl ketones in the presence of a number of ruthenium complexes is reported. The oxotriruthenium complex, Ru3O(OOCCH3)7 was used in applying this process for the oxidative transfer dehydrogenation of unsaturated carbinols to unsaturated ketones.Keywords
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