Synthesis, isolation, and characterization of naphtho[2,3-c]thiophen

Abstract
1,3-Dihydronaphtho[2,3-c]thiophen 2-oxide (1) undergoes dehydration when subjected to flash vacuum thermolysis to afford the heretofore elusive naphtho[2,3-c]thiophen (2) as a highly reactive yellow solid.

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