The preparation and crystal structures of two diphenylantimony triacetate hydrolysis products: [Ph2Sb(OAc)2]2O and [(Ph8Sb4O6)·(HOAc)3]·CH2Cl2

Abstract
Diphenylantimony triacetate undergoes ready hydrolysis to give the oxygen-bridged compound [Ph2Sb(OAc)2]2O containing seven-coordinate antimonyl(V) atoms, and [(Ph8Sb4O6)(HOAc)3] containing a non-adamantane Sb4O6 cage.

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