FURTHER EVIDENCE ON THE ORIGINS OF THE PFEIFFER EFFECT USING CIRCULAR DICHROISM
- 1 August 1973
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 3 (1) , 85-89
- https://doi.org/10.1080/00958977308073791
Abstract
The origins of the Pfeiffer Effect are characterized as zero and first order asymmetric transformations. Direct spectroscopic evidence using circular dichroism is presented for both types of transformations. Based on non-empirical criteria, the circular dichroism spectra obtained from the first order assymmetric transformations are used to characterize the absolute configuration of the enantiomer present in greater concentration.Keywords
This publication has 32 references indexed in Scilit:
- Partial photoresolution of tris(1,10-phenanthroline)chromium(III) using an analog of the Pfeiffer effectJournal of the American Chemical Society, 1971
- A Study of the Pfeiffer Effect in Systems containing Trisoxalatometallate(III) Complexes and Cinchonine HydrochlorideCanadian Journal of Chemistry, 1971
- Induced optical rotation and circular dichroism of some symmetric group IV metal halidesJournal of the American Chemical Society, 1971
- Induced optical rotation — the Pfeiffer Effect and C.D. of some racemic group(IV) metal complexesInorganic and Nuclear Chemistry Letters, 1971
- The application of the Pfeiffer effect to the resolution of dissymmetric coordination compoundsJournal of the American Chemical Society, 1968
- Asymmetric syntheses, asymmetric transformations, and asymmetric inductions in an optically active solventJournal of the American Chemical Society, 1967
- The Circular Dichoism of [PtXl4]2-IonJournal of the American Chemical Society, 1966
- The Absorption and the Circular Dichroism Spectra and the Absolute Configuration of the Tris Acetylacetonato Silicon(IV) Ion.Acta Chemica Scandinavica, 1966
- The kinetics of racemization of optically active complex ions of group 8 elements. Part 3.—tris-1: 10-Phenanthroline and tris-2: 2′-dipyridyl nickel ions in solutions of other optically active ionsTransactions of the Faraday Society, 1954
- Configurational ActivityNature, 1951