A New Valence Tautomerism Example in an Electroactive Ferrocene Substituted Triphenylmethyl Radical
- 15 January 2003
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (6) , 1462-1463
- https://doi.org/10.1021/ja0282590
Abstract
A new molecular system combining an open-shell organic radical that acts as an acceptor group, different from an o-quinone moiety, covalently linked to a ferrocene moiety, acting as the donor group, is shown to exhibit valence tautomerism.Keywords
This publication has 11 references indexed in Scilit:
- Valence Tautomerism and Metal-Mediated Catechol Oxidation for Complexes of Copper Prepared with 9,10-PhenanthrenequinoneInorganic Chemistry, 2001
- New Molecular Assemblies of Redox Isomers, [CrIII(X4SQ)3-n(X4Cat)n]-n (X = Cl and Br; n = 0, 1, and 2), with Metallocenium Cations, [MIIICp2]+ (M = Co and Fe): X-ray Crystal Structures and Physical PropertiesInorganic Chemistry, 2000
- Redox-Tunable Valence Tautomerism in a Cobalt Schiff Base ComplexInorganic Chemistry, 2000
- Ferromagnetic interactions between triphenylmethyl radicals through an organometallic couplerChemical Communications, 1999
- Valence Tautomerism in a Cobalt Complex of a Schiff Base Diquinone LigandInorganic Chemistry, 1998
- Valence tautomeric cobalt o-quinone complexes in a dual-mode switching arrayChemical Communications, 1998
- Valence Tautomeric Interconversion in Transition Metal 1,2‐Benzoquinone ComplexesAngewandte Chemie International Edition in English, 1997
- Pressure-Induced Valence Tautomerism in Cobalto-Quinone Complexes: An X-ray Absorption Study of the Low-Spin [CoIII(3,5-DTBSQ)(3,5-DTBCat)(phen)] to High-Spin [CoII(3,5-DTBSQ)2(phen)] InterconversionInorganic Chemistry, 1996
- Tautomeric catecholate-semiquinone interconversion via metal-ligand electron transfer. Structural, spectral, and magnetic properties of (3,5-di-tert-butylcatecholato)(3,5-di-tert-butylsemiquinone)(bipyridyl)cobalt(III), a complex containing mixed-valence organic ligandsJournal of the American Chemical Society, 1980
- Mössbauer SpectroscopyPublished by Springer Nature ,1971