Synthesis and spectroscopic studies of inorganic tin derivatives of amino-acids and their esters
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 2,p. 439-444
- https://doi.org/10.1039/dt9820000439
Abstract
The nature of the product obtained on reacting SnCl2 with sulphur-containing amino-acids is shown to depend on the reaction conditions. Eleven new inorganic tin(II) or tin(IV) derivatives of sulphur-containing amino-acids and their esters are reported. Three tin(II) complexes of amino-acids that have exclusively Sn–O bonds have also been prepared. The bonding in these compounds is discussed in terms of their i.r. and l19Sn Mössbauer spectroscopic data. Infrared spectra suggest the presence of co-ordination to Sn by the amino-N atoms.This publication has 1 reference indexed in Scilit:
- Structural characterization of a bridged 99Tc-Sn-dimethylglyoxime complex: implications for the chemistry of 99mTc-radiopharmaceuticals prepared by the Sn (II) reduction of pertechnetate.Proceedings of the National Academy of Sciences, 1976