Stochastic Model for Gel-Permeation Chromatography at High Flow Rates
- 1 December 1968
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 49 (11) , 5161-5162
- https://doi.org/10.1063/1.1670016
Abstract
Calculations are presented for the elution curve of monodisperse polymer obtained during gel-permeation chromatography at high flow rates. The derivation parallels an earlier stochastic treatment by McQuarrie valid at low flow rates. Under those conditions the result of the present model reduces to that obtained by McQuarrie.Keywords
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