A large enhancement in the binding affinity of artificial hosts by OsVI chelation
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 20,p. 2069-2070
- https://doi.org/10.1039/a906252a
Abstract
Mononuclear OsVI-chelated macrocycles, self-assembled from OsO4, 2,3-dimethylbut-2-ene and bispyridyl ligands, bind diamides much more strongly than the OsVI-free ligands (ΔΔG = –14.6 kJ mol–1).Keywords
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