Hydrolysis and selective reduction with yeast: enantiospecific synthesis of antirhine from secologanin
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 825-826
- https://doi.org/10.1039/c39910000825
Abstract
Glucoside hydrolysis and chemoselective reduction of secologanin ethylene acetal 2 with baker's yeast affords a C-1 reduced aglucone 4 from which (+)-antirhine 8 is obtained in a four-step sequence.Keywords
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