Silicon Nitride Films with Low Hydrogen Content, Low Stress, Low Damage and Stoichiometric Composition by Photo-Assisted Plasma CVD

Abstract
A photo-assisted plasma CVD method was developed to deposit high quality silicon nitride films. Nitrogen gas excited in a high density plasma kept apart from a wafer was effectively transported to the deposition chamber under the Knudsen pressure region and reacted with silane gas to generate intermediates. The adsorbed intermediates on the wafer were photo-excited to produce silicon nitride film. Silicon nitride films with the hydrogen content of 3–7 atm%, the density of 2.9–3.3 g/cm3, the tensile stress of 0.5–3.0×109 dyn/cm2 and the Si/N composition of 0.75 were successfully deposited at 300°C.

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