Alk-2-en-4-yn-1-ols and furans from alkali-metal acetylides and epichlorohydrin
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- p. 2283-2285
- https://doi.org/10.1039/j39660002283
Abstract
The preparation of trans-undec-2-en-4-yn-1-ol, trans-hept-2-ene-4,6-diyn-1-ol and trans-non-2-ene-4,6-diyn-1-ol from the reaction of alkali-metal acetylides and diacetylides with epichlorohydrin is described. 2-Furylallene and 1-(2-furyl)prop-1-yne, believed to originate from the cyclisation of cis-hept-2-ene-4,6-diyn-1-ol, were also isolated. trans-3-Chloroprop-2-en-1-ol is shown to be a by-product in the preparation of trans-pent-2-en-4-yn-1-ol.Keywords
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