Time and length scales in supercooled liquids
- 27 February 2004
- journal article
- Published by American Physical Society (APS) in Physical Review E
- Vol. 69 (2) , 020201
- https://doi.org/10.1103/physreve.69.020201
Abstract
We numerically obtain a quantitative demonstration that development of spatial correlations of mobility as temperature is lowered is responsible for the “decoupling” of transport properties of supercooled liquids. This result further demonstrates the necessity of a spatial description of the glass formation and therefore seriously challenges a number of popular alternative theoretical descriptions.Keywords
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This publication has 34 references indexed in Scilit:
- Self-Diffusion oftris-Naphthylbenzene near the Glass Transition TemperaturePhysical Review Letters, 2003
- Supercooled liquids and the glass transitionNature, 2001
- Spatially Heterogeneous Dynamics in Supercooled LiquidsAnnual Review of Physical Chemistry, 2000
- Heterogeneity at the glass transition: a reviewJournal of Non-Crystalline Solids, 1999
- Enhanced translation of probe molecules in supercooled o-terphenyl: Signature of spatially heterogeneous dynamics?The Journal of Chemical Physics, 1996
- Measuring diffusion in supercooled liquids: The effect of kinetic inhomogeneitiesThe Journal of Chemical Physics, 1996
- Breakdown of the Stokes–Einstein relation in supercooled liquidsThe Journal of Chemical Physics, 1995
- Stokes-Einstein violation in glass-forming liquidsPhysical Review E, 1993
- Translational and rotational diffusion in supercooled orthoterphenyl close to the glass transitionZeitschrift für Physik B Condensed Matter, 1992
- Diffusion, viscosity and structural slowing down in soft sphere alloys near the kinetic glass transitionChemical Physics, 1990