Studies on the Synthesis of Eremophilane Sesquiterpenes. A Novel Entry into the Aristolane Ring System
- 1 December 1986
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 16 (14) , 1789-1798
- https://doi.org/10.1080/00397918608057202
Abstract
Readily available tricyclo[3.2.2.02,4]non-6-en-8-one is converted into the tricyclo ring system of the aristolane sesquiterpenes via an alkoxide accelerated [3, 3]-sigmatropic rearrangement.Keywords
This publication has 16 references indexed in Scilit:
- An aristolane sesquiterpenoid from the sea pen Scytalium splendensThe Journal of Organic Chemistry, 1983
- Stereochemistry and product distribution in the singlet oxygen cycloaddition with 7,7‐disubstituted 1,3,5‐cycloheptatrienesEuropean Journal of Inorganic Chemistry, 1983
- Cycloheptatriene und Norcaradiene1): Zusammenhang zwischen Rotationsbehinderung um die C‐7–C‐8‐Bindung und StrukturEuropean Journal of Inorganic Chemistry, 1982
- Stereochemical study of the [3,3] sigmatropic rearrangement of 1,5-diene-3-alkoxides. Application to the stereoselective synthesis of (.+-.)-juvabioneJournal of the American Chemical Society, 1980
- Zur Stereochemie der Norcaradien‐Norcaradien‐Umlagerung, I. Die Synthese optisch aktiver [Norcaradien ⇌ Cycloheptatrien]‐DerivateEuropean Journal of Inorganic Chemistry, 1977
- [3,3]Sigmatropic rearrangements of 1,5-diene alkoxides. Powerful accelerating effects of the alkoxide substituentJournal of the American Chemical Society, 1975
- Δ1(10)‐Aristolenon‐(2) und 1.8.9.10‐Tetradehydro‐aristolanon‐(2), neue Sesquiterpen‐ketone vom Aristolan‐TypEuropean Journal of Organic Chemistry, 1968
- Valence Isomerizations of C9H10 HydrocarbonsAngewandte Chemie International Edition in English, 1968
- Terpenes - XVII structure of calarene and stereochemistry of aristoloneTetrahedron Letters, 1962
- Über Dien‐Synthesen mit Cyclohepta‐trien‐(1.3.5)European Journal of Inorganic Chemistry, 1953